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Q.

The first ionisation energies of the elements of the first transition series:

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a

increase as the atomic number increase.

b

decrease as the atomic number increase.

c

do not show any change as the addition of electrons takes place in the inner (n - 1) d-orbitals.

d

increase from Ti to Mn and then decrease from Mn to Cu.

answer is A.

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Detailed Solution

First ionisation energies of 3d-series (first transition series) increase with increase in atomic number due to (i) increase in nuclear charge (ii) decrease in atomic size.
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The first ionisation energies of the elements of the first transition series: