The first IP of lithium is 5.41eV and electron affinity of Cl is -3.61eV. Calculate ΔH in KJmol–1 for the reaction Li(g) + Cl(g) → Li(g)+ + Cl–(g)
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a
173.7
b
-173.7
c
1.73
d
17.3
answer is A.
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Detailed Solution
IP1 of Li is 5.41ev and EA of Cl is 3.6 evLi(g) → Li+(g) ΔH=+5.41evCl(g) → Cl-(g) ΔH=-3.6evΔH = 1.8(96.45) = +173.7 KJLi(g) + Cl(g) → Li+(g) + Cl-(g) ΔH=+1.8ev