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Q.

99% of a first order reaction was completed in 32 min. When will 99.9% of the reaction complete ?

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answer is 4.

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Detailed Solution

2.30332log100100-99=2.303t99.9log100100-99.9 116=3t99.9 t99.9=16×3=48 min
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99% of a first order reaction was completed in 32 min. When will 99.9% of the reaction complete ?