Q.

Fluorine has the highest electronegativity among the group on the Pauling scale, but the electron affinity of fluorine is less than that of chlorine because

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a

The atomic number of fluorine is less than that of chlorine

b

Fluorine being the first member of the family behaves in an unusual manner

c

Chlorine can accommodate an electron better than fluorine by utilizing its vacant 3d orbital

d

Small size, high electron density and an increased electron repulsion make the addition of an electron to fluorine less favourable than that in the case of chlorine

answer is D.

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Detailed Solution

When electron is added to the Valence shell, it faces repulsion with the existing electron cloud, hence its less EA than Cl only.
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