Q.
Fluorine has the highest electronegativity among the group on the Pauling scale, but the electron affinity of fluorine is less than that of chlorine because
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a
The atomic number of fluorine is less than that of chlorine
b
Fluorine being the first member of the family behaves in an unusual manner
c
Chlorine can accommodate an electron better than fluorine by utilizing its vacant 3d orbital
d
Small size, high electron density and an increased electron repulsion make the addition of an electron to fluorine less favourable than that in the case of chlorine
answer is D.
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Detailed Solution
When electron is added to the Valence shell, it faces repulsion with the existing electron cloud, hence its less EA than Cl only.
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