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Q.

For the following acidsI   CH33CCH2CO2H            II   CH33N⊕CH2CO2H             III   CH3COOHpKa  value will be in order

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a

I > II > III

b

l < lI < lII

c

I > III > II

d

II > III > I

answer is C.

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Detailed Solution

EWG increases acidic strength  −I,  −mEDG decreases acidic strength pKa  ∝   1KaKa ∝ Stability of carboxylate ion.Stability of ion is II > III > I⇒  Ka  II  >  III  >  IpKa II  <  III  < I
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