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Q.

Of the following alcohols, the one that would react fastest with conc. HCl and anhydrous ZnCl2  is :

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a

Butan-1-ol

b

Butan-2-ol

c

2-methylpropan-2-ol

d

2-methylpropanol

answer is C.

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Detailed Solution

R−OH+HCl→ZnCl2anhydrous   R−Cl+H2O.This is the reaction of alcohols with Lucas reagent. It involves C – O Cleavage.Rate of reactivity …….   R3COH>R2CHOH  >   RCH2OH30-alcohols give immediate turbidity20-alcohols give turbidity in few minutes10-alcohols do not give turbidity at room temperature.CH33C-OH is a 30 alcohol30-alcohols which gives immediate turbidity.
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