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Q.

The following compound is least reactive towards nucleophilic substitution

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a

b

c

CH2=CH-CH2-Cl

d

CH3-CH2-Cl

answer is A.

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Detailed Solution

In aryl and vinyl halides, C-Cl bond acquires double bond character due to resonance;They are least reactive towards nucleophilic substitution;Moreover it is difficult to remove chloride ion from a more electronegative sp2 carbon;Thus in the above list, the least reactive compound is chloro benzene;
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The following compound is least reactive towards nucleophilic substitution