Q.

In the following disproportionation of Cl2 in basic mediumCl2 + 2KOH  →  KCl  + KClO + H2OEquivalent mass of  Cl2 is

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a

35.50

b

71.00

c

47.33

d

11.83

answer is B.

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Detailed Solution

In a disproportionation reactionnew equivalent mass = E (oxidation part) + E (reduction part) Net = M2 + M2 = M = 71.0
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In the following disproportionation of Cl2 in basic mediumCl2 + 2KOH  →  KCl  + KClO + H2OEquivalent mass of  Cl2 is