Q.

Of the following order of reactivity of Cl with AgNO3, which one is correct?

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a

CH2 = CH –CH2Cl > CH3CH2CH2Cl > CH3CH =CHCl

b

CH2 = CH –CH2Cl > CH3CH2CH2Cl < CH3CH =CHCl

c

CH2 = CH –CH2Cl < CH3CH2CH2Cl > CH3CH =CHCl

d

CH2 = CH –CH2Cl < CH3CH2CH2Cl <  CH3CH =CHCl

answer is A.

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Detailed Solution

CH2=CHCH2Cl is an allylic chloride that reacts with AgNO3  in the cold to give a white precipitate of AgCl. CH3CH2CH2Cl gives a precipitate on warming. CH3CH=CHCl is a vinylic chloride which is inert even when heated.Hence, the correct answer is (1).
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