Questions
Of the following order of reactivity of Cl with AgNO3, which one is correct?
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By Expert Faculty of Sri Chaitanya
a
CH2 = CH –CH2Cl > CH3CH2CH2Cl > CH3CH =CHCl
b
CH2 = CH –CH2Cl > CH3CH2CH2Cl < CH3CH =CHCl
c
CH2 = CH –CH2Cl < CH3CH2CH2Cl > CH3CH =CHCl
d
CH2 = CH –CH2Cl < CH3CH2CH2Cl < CH3CH =CHCl
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Correct option is A
CH2=CHCH2Cl is an allylic chloride that reacts with AgNO3 in the cold to give a white precipitate of AgCl. CH3CH2CH2Cl gives a precipitate on warming. CH3CH=CHCl is a vinylic chloride which is inert even when heated.Hence, the correct answer is (1).Similar Questions
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