The following process has been used to obtain iodine from oil-field brines in California.NaI + AgNO3 → AgI + NaNO3 .....12AgI + Fe → FeI2 + 2Ag ......22FeI2 + 3Cl2 → 2FeCl3 + 2I2 .......3How many grams of AgNO3 are required in the first step for every 254 kg I2 produced in the third step ?
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a
340 × 103
b
240 × 103
c
440 × 103
d
540 × 103
answer is A.
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Detailed Solution
Balanced equation : Balance the given series of equations to get 2 moles of IodineNaI + AgNO3 → AgI + NaNO3 .....1×4⇒4NaI+4AgNO3→4AgI+4NaNO32AgI + Fe → FeI2 + 2Ag ......2×2⇒4AgI + 2Fe → 2FeI2 + 4Ag2FeI2 + 3Cl2 → 2FeCl3 + 2I2 .......3Hence 4 moles of AgNO3→2 moles of I2 4×170g of AgNO3 → 2×254g ? → 254×103gmass of AgNO3 required = 254×1032×254×4×170 = 340×103g