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Q.

For the following reaction : K=1.7×107  at 250C Ag(aq)++2NH3(aq)⇌[Ag(NH3)2]⊕  then ΔG0  in KJ  is

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a

−17.9

b

+17.9

c

−41.25

d

+41.25

answer is C.

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Detailed Solution

ΔG0=−2.303  RT  logKc =−2.303×8.314×10−3×298×log(1.7×107)KJ/mole =−2.030×8.314×0.298×7.2304   KJ/mole =−41.25    KJ/mole
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