In the following reaction (unbalanced), equivalent weight of As2S3 is related to molecular weight M byAs2S3 + H+ + NO3- → NO + H2O + AsO43- + SO42-
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a
M2
b
M4
c
M28
d
M24
answer is C.
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Detailed Solution
As+32S-23 → As+5O43- + 3S+6O42-Change in ox. state of ‘As’ = 2(2) = 4Change in Ox. state of ‘S’ = 3(8) = 24Net change in Oxidation state = 28 Thus, equivalent mass of As2S3 = M28