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Q.

In the following reactions which is deuterolysisI) AlCl3 + 3D2O → Al(OD)3 + 3DClII) CaC2 + 2D2O → Ca(OD)2 + C2D2III) Mg3P2 + 6D2O → 3Mg(OD)2+ 2PD3

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a

I and II only

b

II and III only

c

I and III only

d

I, II and III

answer is D.

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Detailed Solution

Deuterolysis means addition of Deuterated water to a compound in the form of D+ & OD- . During Deuterolysis cleavage of bonds in the compound takes place
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In the following reactions which is deuterolysisI) AlCl3 + 3D2O → Al(OD)3 + 3DClII) CaC2 + 2D2O → Ca(OD)2 + C2D2III) Mg3P2 + 6D2O → 3Mg(OD)2+ 2PD3