The following reacts with water to give H2O2
H2SO4
H2S2O8
PbO2
MnO2
If you take 1:1 ratio of H2O and H2S2O8 the we will get Sulphuric acid and peroxymono sulphuric acid
If you take 1:2 ratio of H2S2O8 & H2O then we will get 2:1 ratio of H2SO4 & H2O2.
H2S2O8→ 2H2O1 mole2H2SO4+1H2O2