The formation of the oxide ion" O-2(g) " requires first an exothermic and then an endothermic step as shown below ;O(g) + e– → O–(g); ΔH0 = – 142kJmol–1 ; O–(g) + e– → O(g)-2; ΔH0 = 844 kJmol–1. This is because
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a
O– ion will tend to resist the addition of another electron
b
Oxygen has high electron affinity
c
Oxygen is more electronegative
d
O–ion has comparatively larger size than oxygen atom
answer is A.
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Detailed Solution
The negative charge of O-(g) repels the incoming electron and thus O-(g) → O-2 is endothermic
The formation of the oxide ion" O-2(g) " requires first an exothermic and then an endothermic step as shown below ;O(g) + e– → O–(g); ΔH0 = – 142kJmol–1 ; O–(g) + e– → O(g)-2; ΔH0 = 844 kJmol–1. This is because