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Q.

The formation of the oxide ion" O-2(g) " requires first an exothermic and then an endothermic step as shown below ;O(g) + e– → O–(g);    ΔH0 = – 142kJmol–1  ; O–(g) + e– → O(g)-2;  ΔH0 = 844 kJmol–1. This is because

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a

O– ion will tend to resist the addition of another electron

b

Oxygen has high electron affinity

c

Oxygen is more electronegative

d

O–ion has comparatively larger size than oxygen atom

answer is A.

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Detailed Solution

The negative charge of O-(g) repels the incoming electron and thus O-(g) → O-2 is endothermic
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The formation of the oxide ion" O-2(g) " requires first an exothermic and then an endothermic step as shown below ;O(g) + e– → O–(g);    ΔH0 = – 142kJmol–1  ; O–(g) + e– → O(g)-2;  ΔH0 = 844 kJmol–1. This is because