The formation of PH4⊕ is difficult compared to NH4⊕ because:
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a
lone pair of phosphorus is optically inert
b
lone pair of phosphorus resides in almost pure p-orbital
c
lone pair of phosphorus resides at sp3 orbital
d
lone pair of phosphorus resides in almost pure s-orbital
answer is D.
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Detailed Solution
The formation of PH4+ is difficult compared to NH4+ because lone pair of phosphorus resides in almost pure s-orbital.Due to this, phosphine lacks nucleophilicity and the donation of the lone pair to a proton becomes difficult.In ammonia, the lone pair is present in sp3 hybrid orbital and can be easily donated to proton.