From the information given in the passage, what is the most likely configuration of the cobalt d-electrons for the species (A) CoCl63− and (B) CoNO263−?
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a
both (A) and (B) have low spin
b
(A) has high spin; (B) has low spin
c
(A) has low spin; (B) has high spin
d
Both (A) and (B) have high spin
answer is B.
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Detailed Solution
Cl⊖ always behaves as weak field ligand so high spin complex formed. Also here ∆o is not sufficient to overcome pairing energy P, NO2Θ with Co behaves as strong field ligand and hence low spin complex. Also ∆o > P and hence pairing takes place.