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Q.

4.8 g of C (diamond) on complete combustion evolves 1584 kJ of heat. The standard heat of formation of gaseous carbon is 725 kJ/mol. The energy required for the process(i) C(graphite) →  C(gas)(ii) C(diamond) →  C(gas) are

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a

725, 727

b

725, 725

c

725, 723

d

none of these

answer is C.

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Detailed Solution

The expression for standard heat of formation of gaseous carbon isC(graphite) →  C(gas)∆H=725 kJ/molAs graphite is thermodynamically more stable than diamond so the heat required to convert graphite to gaseous carbon should be more.
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