4.8 g of C (diamond) on complete combustion evolves 1584 kJ of heat. The standard heat of formation of gaseous carbon is 725 kJ/mol. The energy required for the process(i) C (graphite) → C (gas)(ii) C (diamond) →C (gas) are
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a
725, 727
b
727, 725
c
725, 723
d
none of these
answer is C.
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Detailed Solution
The expression for standard heat of formation of gaseous carbon isC (graphite) → C (gas)∆H = 725 kJ/molAs graphite is thermodynamically more stable than diamond so the heat required to convert graphite to gaseous carbon should be more.