25 g ethylene glycol is present in 100 g of water. The solution is cooled to–10°C. Kf for H2O is 1.86 K kg mol–1. The amount of ice separated on cooling is
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a
25 g
b
50 g
c
75 g
d
20 g
answer is A.
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Detailed Solution
∆Tf=Kf×wm×1000WIn gms10=1.86×2562×1000WWweight of solvent= 75 grwglycol remains constant on cooling; only water freezes Therefore, Ice separated =WH2o initial taken-WH2Oremaining =100-75=25 gm