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Q.

8 g of O2 gas at 27°C is compressed to half of the volume under isothermal and reversible condition. Work done (in cal) on the system is

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a

W = 0

b

W = 2.303x 150 log2

c

W = -2.303 x 150 log2

d

W = -2.303 x 300 x 8 x 2 log 2

answer is C.

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Detailed Solution

Work done =2.303 nRT log⁡V2V1=2.303×14×2×300 log12=(−2.303×150 log2 ) cal
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