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108 g of silver (molar mass 108 g  mol−1) is deposited at cathode from AgNO3aq  solution by  a certain quantity of  electricity. The volume  (in L) of oxygen gas produced at 273 K and 1 bar pressure from water by the same quantity of electricity is

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answer is 5.67.

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Detailed Solution

2H2O→4H++O2+4e−                4moles  of  e-→1 Mole of  O2 1mole  of  e-→1 4Mole of  O2          Vm=nRTp=1×8.314×273100=22.697L For  14  mol of O2,   V=5.67 L
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108 g of silver (molar mass 108 g  mol−1) is deposited at cathode from AgNO3aq  solution by  a certain quantity of  electricity. The volume  (in L) of oxygen gas produced at 273 K and 1 bar pressure from water by the same quantity of electricity is