A gas absorbs 100 J of heat and is simultaneously compressed by a constant external pressure of 1.50 atmospheres from a volume of 8 L to 2 L. ∆E will be
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a
-812 J
b
812 J
c
1011 J
d
911 J
answer is C.
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Detailed Solution
ΔH=100J Work done PΔV=1.5(−6). Now, this work done is in liter atmospheres. To obtain the same in joules, multiply by 8.314 and divide by 0.0821.∴ΔH=ΔE+PΔV Or, 100=ΔE+1.5(−6)0.0821×8.314 Or, ΔE=1011.4J