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Q.

Gaseous cyclobutene isomerizes to butadiene in a first order process which has a k value at 153°C of 3.3 x 10-4 s-1. How may minutes would it take for the isomerization to proceed 40% to completion at this temperature?

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a

26 min

b

52 min

c

13 min

d

None of these

answer is A.

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Detailed Solution

t=2.33.3×10−4×60min−1log⁡100100−40 Solve for t≈26min.

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Gaseous cyclobutene isomerizes to butadiene in a first order process which has a k value at 153°C of 3.3 x 10-4 s-1. How may minutes would it take for the isomerization to proceed 40% to completion at this temperature?