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Q.

A gaseous system undergoes a change of state from (A) to (B) by any of the given path. Path I or path II as shown in figureAs per path I,Δq=−400cal and ΔW=14cal As per path II, Δq=−48 cal.   Therefore work done, ΔW in path (II) is

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a

- 338 cal

b

- 366 cal

c

- 434 cal

d

- 462 cal

answer is A.

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Detailed Solution

For path I  ΔEI=Δq+ΔW=−400+14=−386cals For path II,  ΔEII=ΔEI=−48+ΔW∴ ΔW=−386+48=−338cal
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