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Q.

In general boiling point of covalent compounds is affected due to  increasing molecular weight and  hydrogen  bonding.  Thus it is observed that the boiling point of octanol  is greater that water while  that of methanol is lesser than water.  The other  properties which are considerably affected due to  hydrogen bond formation are acidic nature, melting  point, anomalous behaviour  of water below 4°C .,  It is therefore concluded that hydrogen bonding plays a vital role in explaning  many   observable facts.Which among the following has maximum boiling point?Ka2  of Maleic acid is lesser than Ka2 of fumaric acid due to:For which of the following the value of Ka is minimum?

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answer is [OBJECT OBJECT], [OBJECT OBJECT], [OBJECT OBJECT].

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Detailed Solution

High packing and strong hydrogen bond. If branching increases then hydrogen bonding decreases.The stability of the conjugate base.Groups at meta position creates less minus I, and due to which O-H bonds cleaves slow.
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