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a
Free rotation about C -C
b
Restricted rotation about C = C
c
Restricted rotation about C≡C
d
Free rotation about C = C
answer is B.
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Detailed Solution
The isomers which are obtained due to the restricted rotation about C=C double bond are said to be Geometrical isomers,and the phenomena is said to Geometrical isomerism.→ The restricted rotation about carbon-carbon double bond in -2-butene is due to sidewise overlap of two p-orbitals.