Q.
The geometry and magnetic behaviour of the complex Ni(CO)4 are
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a
square planar geometry and diamagnetic
b
tetrahedral geometry and diamagnetic
c
square planar geometry and paramagnetic
d
tetrahedral geometry and paramagnetic.
answer is B.
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Detailed Solution
Ni(28):[Ar]3d84s2∵ CO is a strong field ligand, so, unpaired electrons get paired Thus, the complex is sp3 hybridised with tetrahedral geometry and diamagnetic in nature.
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