Q.

Give decreasing order of the following towards Nucleophilic Addition reaction.

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a

(I) > (II) > (III) > (IV)

b

(IV) > (III) > (II) > (I)

c

(II) > (III) > (IV) > (I)

d

(I) > (IV) > (III) > (II)

answer is C.

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Detailed Solution

All are aldehydes, – I effect of Cl at C -2 > at C – 3 > at C – 4. More the – I effect, more reactive is the tendency of aldehyde towards Nucleophilic Addition  reaction [(II) > (III) > (IV) > (I)].
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