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Q.

Give the decreasing order of Ka value of the following compounds.

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a

(I) > (IV) > (III) > (II)

b

(II) > (III) > (IV) > (I)

c

(I) > (III) > (II) > (IV)

d

(I) > (IV) > (II) > (III)

answer is A.

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Detailed Solution

Therefore, the order of acidic character:Aromatic > Non-aromatic > Anti-aromatic.But anti-aromaticity of (III) is more than (II) since (III) is moreresonance stabilised than (II).Therefore, the order of decreasing acidic character or Ka value is (I)>(IV)>(III)>(II).
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