Give the decreasing order of Ka value of the following compounds.
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a
(I) > (IV) > (III) > (II)
b
(II) > (III) > (IV) > (I)
c
(I) > (III) > (II) > (IV)
d
(I) > (IV) > (II) > (III)
answer is A.
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Detailed Solution
Therefore, the order of acidic character:Aromatic > Non-aromatic > Anti-aromatic.But anti-aromaticity of (III) is more than (II) since (III) is moreresonance stabilised than (II).Therefore, the order of decreasing acidic character or Ka value is (I)>(IV)>(III)>(II).