Given below are two statements:Statement I: o-Nitrophenol is steam volatile due to intramolecular hydrogen bonding.Statement II: o- Nitrophenol has high melting due to hydrogen bonding.In the light of the above statements, choose the most appropriate answer from the options given below:

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Both Statement I and Statement II are false

Statement I is true but Statement II is false

Both Statement I and statement II are true

statement I is false but Statement II is true

answer is B.

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Detailed Solution

o- Nitrophenol - intramolecular hydrogen bonding-more volatile (i.e) lower B.Pp-nitrophenol-intramolecular hydrogen bonding – less volatile-(i.e) higher B.Pp-nitrophenol has higher M.P because if its symmetric structure which may lead to close packing in solid state

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