Q.
Given that ∧m∞=133.4AgNO3∧m∞=149.9(KCl);∧m∞=144.9Scm2mol−1KNO3 the molar conductivity at infinite dilution for AgCl is:
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answer is 2.
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Detailed Solution
Λm∞ AgNO3 = Λm∞ Ag+ + Λm∞ NO3− = 133.4 sm2 mole−1 ..........(1)Λm∞ KCl = Λm∞ K+ + Λm∞ Cl − = 149.9 sm2 mole−1 ............(2)Λm∞ KNO3 = Λm∞ K+ + Λm∞ NO3− = 144.9 sm2 mole−1 ............(3) Λm∞ AgCl = Eq1 + Eq2 − Eq3= (133.4 + 149.9 – 144.9)Scm2 mole–1 = 138.4 Scm2 mole–1
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