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Q.

A graph plotted between Δf0G  vs  Ttemperature is drawn below.This graphical representation is consistent with the reaction

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a

2Mgs+O2g→2MgOs

b

Cs+O2g→CO2g

c

2Cs+O2g→2COg

d

2COg+O2g→2CO2g

answer is C.

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Detailed Solution

ΔoS is -ve for option (1)and (4).∆0S is zero in option (2)ΔoS is +ve for option (3).ΔoG=ΔoH−TΔ0S.ΔoS  +ve…. as temperature increases, ΔoG decreases.ΔoS  −ve ….as temperature increases, ΔoG increases.
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