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H2O4CoO22CoH2O4SO42[X] reagent H2O4CoO22CoH2O4SO4

In both the complex Co has t2g6eg0 configuration.  Correct options among the following ?

 

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a
Complex (I) is Paramagnetic
b
Complex (II) is Diamagnetic
c
(X) is oxidizing agent
d
(X) is reducing agent

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detailed solution

Correct option is A

In H2O4CoO22CoH2O4SO42 Bridged ligand is O2− (superoxide)\paramagneticIn H2O4CoO22CoH2O4SO4 Bridged ligand is O22− (peroxide)\DiamagneticO2-⟶ 'X'reductant O22-

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