Q.
H2O4CoO22CoH2O4SO42⟶[X] reagent H2O4CoO22CoH2O4SO4In both the complex Co has t2g6eg0 configuration. Correct options among the following ?
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a
Complex (I) is Paramagnetic
b
Complex (II) is Diamagnetic
c
(X) is oxidizing agent
d
(X) is reducing agent
answer is A.
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Detailed Solution
In H2O4CoO22CoH2O4SO42 Bridged ligand is O2− (superoxide)\paramagneticIn H2O4CoO22CoH2O4SO4 Bridged ligand is O22− (peroxide)\DiamagneticO2-⟶ 'X'reductant O22-
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