Q.

H2O4CoO22CoH2O4SO42⟶[X] reagent H2O4CoO22CoH2O4SO4In both the complex Co has t2g6eg0 configuration.  Correct options among the following ?

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a

Complex (I) is Paramagnetic

b

Complex (II) is Diamagnetic

c

(X) is oxidizing agent

d

(X) is reducing agent

answer is A.

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Detailed Solution

In H2O4CoO22CoH2O4SO42 Bridged ligand is O2− (superoxide)\paramagneticIn H2O4CoO22CoH2O4SO4 Bridged ligand is O22− (peroxide)\DiamagneticO2-⟶ 'X'reductant O22-
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