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Q.

For H+ the value of λ∞=349.8 S cm2 eq−1. Calculate the mobilities of H+ ion and its velocity if it is in a cell in which the electrodes are 5 cm apart and to which a potential of 2 volts is applied.

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a

3.62×10−3cm2 volt−1 sec−1, 1.45×10−3 cm sec−1

b

5.2×10−4cm2 volt−1 sec−1,2.08×10−4 cm sec−1

c

3.2×10−4cm2 volt−1 sec−1,1.05×10−3 cm sec−1

d

1.43×10−3cm2 volt−1 sec−1,3.575×10−3 cm sec−1

answer is A.

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Detailed Solution

Ionic conductance= 96500×mobility Mobility=349.896500=3.62×10-3 Mobility =VelocityPotential gradiant Velocity=3.62×10-3×25     Potential gradiant=Potential differenceDistance                =1.45×10-3 cm sec-1
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