HCHO→ conc.NaOHA+B;C6H5CHO→conc.KOHP+Q. Correct set is
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a
A=CH3ONa; B=HCOOH ; C=C6H5COOK ; D=C6H5CH2OH
b
A=CH3OH; B=HCOONa ; C=C6H5COOH ; D=C6H5CH2OK
c
A=CH3OH; B=HCOONa ; C=C6H5COOK ; D=C6H5OH
d
A=CH3OH; B=HCOONa ; C=C6H5COOK ; D=C6H5CH2OH
answer is D.
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Detailed Solution
Disproportionation of an aldehyde not containing α-hydrogen atoms in presence of conc.alkali to give a carboxylate ion and alcohol is called Cannizaro's reaction.2HCHO→conc.NaOHHCOO−Na+A+CH3OHB;2C6H5CHO→conc.KOHC6H5COO−K+P+C6H5CH2OHQ