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Q.

HCHO→H2OCH3CH2MgBrA→PCCB; Functional isomer of ‘B’ is

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a

Propanone

b

Propanal

c

Methyl ethanoate

d

Propanoic acid

answer is A.

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Detailed Solution

HCHO→CH3CH2MgBrCH3CH2CH2OMgBr→H2OCH3CH2CH2OH+MgOHBr; PCC is useful in controlled oxidation; 10 alcohols on controlled oxidation give aldehydes; CH3CH2CH2OH→PCCCH3CH2CHO; Functional isomer of CH3CH2 CHO is CH3COCH3;
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HCHO→H2OCH3CH2MgBrA→PCCB; Functional isomer of ‘B’ is