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Q.

Henry’s constant (in kbar) for four gases  α,β,γ and  δ in water at 298 K is given below : density of water =103 kg m-3 at 298 KThis table implies that :

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a

The pressure of a 55.5 molal solution of δ  is 250 bar

b

Solubility of γ at 308 K is lower than at 298 K

c

The pressure of a 55.5  molal solution of γ is 1 bar

d

α has the highest solubility in water at a given pressure

answer is A.

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Detailed Solution

1) Solubility ∝1KHSo, V – has highest solubility2) It is not related to data of the table 3) (P)8=KH8×(x)8(P)8=0.5×103×55.555.5+100018=250bar4) FUV :(P)V=KHV×(x)V(P)V=2×10-5×103×55.555.5+100018=0.01bar
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Henry’s constant (in kbar) for four gases  α,β,γ and  δ in water at 298 K is given below : density of water =103 kg m-3 at 298 KThis table implies that :