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Q.

The high oxidizing power of fluorine is due to

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a

High heat of dissociation and high heat of hydration

b

Low heat of dissociation and high heat of hydration

c

High heat of dissociation and low heat of hydration

d

High electron affinity

answer is B.

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Detailed Solution

Oxidizing power : F2>Cl2>Br2>I2 This is due to:(i)  F2 has high ( -ve) value of enthalpy of hydration due to smallest size of F⊖ ion(ii) F2 has low bond dissociation energy due to weaker F-F bond.Bond energy order: Cl2>Br2>F2>I2
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