Q.

Higher the amount of acid or base used to produce a definite change of pH in a buffer solution, higher will be its buffer capacity.Buffer capacity is maximum under the following conditions.[Salt] = [Acid] for acid buffer solution and [Salt] = [Base] for basic buffer solution.pH of a buffer lies in the range of pka±1. Any buffer solution can be used as buffer up to two units depending on pka or pkb values. When pH = pka or pkb solution is said to be efficient buffer.For preparing a buffer solution of pH = 7.0, which of the buffer system will be selected?A buffer of acetic acid pKa≈4.8with sodium acetate will be, when CH3COOH and CH3COONa are present in equivalent amounts has pH limits equal to:Buffer capacity is maximum when

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a

H3PO4,H2PO4−

b

H2PO4−,HPO42−

c

HPO42−,PO43−

d

H3PO4,PO43−

e

0 to 4.8

f

3.8 to 5.8

g

4.3 to 5.3

h

4.8

i

one mole of NH4CI is added to two moles of NH4OH

j

one mole of NH4CI is added to one mole of NH4OH

k

one mole of NH4CI is added to one mole of NaOH

l

one mole of NaCl is added to one mole of NaOH

answer is , , .

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Detailed Solution

A weak acid and its conjugate base HPO42−.  For acidic buffer when  [salt]  [acid] =110, then pH=pKa−1So, weak acid may be used for preparing buffer solution having pH values lying within the range pKa + 1 and pKa - 1. The acetic acid has a pKa of about 4.8, it may, therefore, be used for making buffer solutions with pH values lying roughly within the range 3.8 to 5.8.Buffer capacity is maximum when [salt] = [base]i.e., pOH = pKb for base buffer under above condition. the buffer is called efficient.
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