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Q.

61% HNO3 (W/W) is converted  to 68%(W/W) HNO3 by             , 68%(W/W)HNO3 is converted to              % by dehydration using conc. H2SO4

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a

Fractional distillation , 78%

b

Fractional distillation , 98%

c

Dehydration , 98%

d

Crystallisation , 98%

answer is B.

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Detailed Solution

HNO3(355K) & H2O(373K) differ in B.P68%(W/W) HNO3+32%(W/W)H2O form a maximum boiling AzeotropeIt further cannot be separated by Fractional distillation.68%(W/W) HNO3 on dehydration using conc.H2SO4 gives 98% (W/W) HNO3
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