61% HNO3 (W/W) is converted to 68%(W/W) HNO3 by , 68%(W/W)HNO3 is converted to % by dehydration using conc. H2SO4
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a
Fractional distillation , 78%
b
Fractional distillation , 98%
c
Dehydration , 98%
d
Crystallisation , 98%
answer is B.
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Detailed Solution
HNO3(355K) & H2O(373K) differ in B.P68%(W/W) HNO3+32%(W/W)H2O form a maximum boiling AzeotropeIt further cannot be separated by Fractional distillation.68%(W/W) HNO3 on dehydration using conc.H2SO4 gives 98% (W/W) HNO3