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Q.

How many of the following orders are correct with respect to their properties indicated ?(i) HCl < HF           -            Boiling point(ii) PH3 < NH3           -            Dipole moment(iii) H2O < D2O       -           Strength of Hydrogen bonding(iv) F2 < Cl2            -           Bond energy(v) H2O < OCl2       -            Bond angle(vi) H2O2 < O2F2    -            Bond length of O–O bond(vii) NaCl < CuCl   -             Covalent character.(viii) SO2< SO3      -            Acidic strength

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answer is 7.

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Detailed Solution

The correct order for bond length is O2F2< H2O2 , since the Bond length of O–O bond in hydrogen peroxide is long due to the presence of Hydrogen which is a neutral group. But flourine is minus I and decreases the bond length,
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