Q.
How much ethyl alcohol (C2H5OH) must be added to 1 L of water so that solution will not freeze at -6oF?(Kf of H2O=1.86omol−1kg)
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a
122 g
b
512 g
c
670 g
d
495 g
answer is D.
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Detailed Solution
−6oF is to be converted into oCF−32180= C100−4−32180=C100∴ C=−20oC∴ ΔTf=20oC1 L H2O=1000 g waterΔTf=1000 Kfw1m1w2w1 (ethyl alcohol)=ΔTfm1w21000 Kf=20×46×10001000×1.86=9200001860=494.6 g
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