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How would N-N bond distance or O-O bond distance change when N₂ changes to $N_{2}^{+} and O_{2} changes to O_{2}^{+} ?$

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a

increase, decrease

b

decrease, increase

c

increases in both the cases

d

decreases in both the cases

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detailed solution

Correct option is A

When N2+ is formed from N2, the electron is lost from the bonding molecular orbital and thus the bond order decreases. Consequently, the bond distance increases. When O2+ is formed, the electron is lost from an antibonding molecular orbital. Obviously, the bond order increases and the bond distance decreases.

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