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a
sp3d , sp3d2
b
sp3d2 , sp3d
c
sp3d2 , sp3
d
sp3 , sp3d
answer is C.
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Detailed Solution
Solid PCl5 exists as ionic solid[PCl4]+ [PCl6]-[PCl4]+ ---- 4 bond pairs and no lone pairs -- sp3 -- Tetrahedral[PCl6]- --- 6 bond pairs and no lone pairs -- sp3d2 -- Octahedral