Q.
Hydration energies of Li+ and Cl− are -499 and -382 k.J mole−1. If lattice energy of LiCl is +840 k.J mole−1, heat of solution of LiCl is
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a
+41 kJ mole−1
b
-12.22 kJ mole-1
c
– 1621 kJ mole−1
d
– 41 kJ mole−1
answer is D.
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Detailed Solution
ΔHLiClSol=ΔHLiClHydration+Latticeenergy=−499+(−382)+840=−41kJ/mol
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