Q.

Hydrazine reacts with KIO3 in presence of HCI as  N2H4+IO3−+2H++Cl−⟶ICl+N2+3H2OThe equivalent masses of N2H4 and KIO3 respectively are: [KIO3 = 214]

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a

8 and 53.5

b

16 and 53.5

c

8 and 35.6

d

8 and 87

answer is A.

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Detailed Solution

N2H4⟶N2 n factor =4∴  Eq. wt=324=8I+5O3−→ I+1 n factor =4∴  Eq. wt=2144=53.4
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Hydrazine reacts with KIO3 in presence of HCI as  N2H4+IO3−+2H++Cl−⟶ICl+N2+3H2OThe equivalent masses of N2H4 and KIO3 respectively are: [KIO3 = 214]