Q.
A hydrogen gas electrode is made by dipping platinum wire in a solution of HCI and pH = 10 and by passing hydrogen gas around the platinum wire at 1 atm pressure. The oxidation potential of electrode would be
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a
0.059 V
b
0.59 V
c
0.118 V
d
0.18 V
answer is B.
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Detailed Solution
For hydrogen electrode, oxidation half-reaction is H2(1 atm )⟶2H+ at pH10+2e− If pH=10,H+=1×10−pH=1×10−10From Nernst equation, E=E∘−0.05912logH+2pH2For hydrogen electrode, E∘=0E=−0.05912log10−1021=−0.0591×22log(10)−10 =0.0591×10×log10=0.59V
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