Hydrolysis of one mole of peroxodisulphuric acid produces
One mole of peroxydisulphuric acid on hydrolysis produces 2moles of sulphuric acid & one mole of H2O2.
If you take 1:1 ratio of H2S2O8 & 1mole of H2O gives Sulphuric acid and peroxymono disulphuric acid
If you take 1:2 ratio of H2S2O8 & H2O then we will get 2:1 ratio of H2SO4 & H2O2.