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Q.

Hydrolysis of sucrose gives, Sucrose +H2O⇌ Glucose + Fructose  Equilibrium constant KC for the reaction is 2×1013 at 300 K. Calculate ΔG° at 300 K.

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a

3.52×105Jmol-1

b

5.12×105 J mol-1

c

7.64×104 J mol-1

d

-7.64×104 J mol-1

answer is D.

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Detailed Solution

ΔG°=-RTlnKC  ∆Go =-2.303 RT log10 KC           =- 2.303×8.314 J mol-1K-1× 300 K log (2×1013)            =-7.64×104 J mol-1
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